Zinc Complex-Based Multifunctional Reactive Lithium Polysulfide Trapper Approaching Its Theoretical Efficiency

نویسندگان

چکیده

The shuttle effect of soluble lithium polysulfides (LPS), which causes rapid capacity fading, remains a lingering issue for lithium-sulfur batteries (LSBs). Herein, we report new type reactive molecule-based LPS trapper, zinc acetate-diethanolamine (Zn(OAc)2·DEA), demonstrates molecular efficiency 1.8 trapping, approaching its theoretical limit 2, is the highest trapping capability reported so far. Furthermore, catalytic Zn2+·DEA on redox sulfur species promotes thermodynamics reduction trapped and decreases energy barrier oxidation Zn(SLi)2·DEA formed in discharging process. LSBs using Zn(OAc)2·DEA as binder, catalyst exhibited excellent long-term cycling stability (with retention 85% after 1000 cycles at rate 0.5C) enhanced performance. This work demonstrated potential this novel multifunctional metal complex-based trapper high-capacity stable LSBs.

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ژورنال

عنوان ژورنال: ACS Applied Materials & Interfaces

سال: 2021

ISSN: ['1944-8244', '1944-8252']

DOI: https://doi.org/10.1021/acsami.1c04483